由铜的元素电势图可得:
EΘMF(Cu^2+/Cu^+ )=2EΘMF(Cu^2+/Cu )-EΘMF(Cu^+/Cu)=0.16v
Cu^2+ + Cu ==== 2Cu^+
EΘMF=EΘMF(Cu^2+/Cu^+ ) - EΘMF(Cu^+/Cu)= -0.36v(说明反应向左进行)
而Cu+ +2Cl^- ====CuCl2^- ; KΘf=3.6*10^5
因为lgKθ=ΖEΘMF/(0.0592V)
可算得EΘMF(Cu+/CuCl2^- )=0.33v(说明反应向生成CuCl2^- 进行)
EΘMF + EΘMF(Cu+/CuCl2^- ) - = -0.03v