在100ml含等物质量的HBr和H2SO4溶液中通入0.01molCL2,有一半Br-变为Br2(已 知Br2能氧化H2SO3).原溶液
A.0.075mol•L-1 B.0.008mol•L-1
C.0.75mol•L-1 D.0.08mol•L-1
人气:236 ℃ 时间:2020-04-10 01:59:09
解答
本题中,Br2还原SO4离子还有剩余.设浓度为X,则0.01molCL2提供0.02mol电子,SO4离子得到2Xmol电子,Br-得到X/2mol电子,根据电阻守恒,2.5*X=0.02,X=0.008mol,因为有100ml溶液,故选择D
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